Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate.

نویسندگان

  • Mathieu Ratel
  • Mathieu Branca
  • Julien Breault-Turcot
  • Sandy Shuo Zhao
  • Pierre Chaurand
  • Andreea R Schmitzer
  • Jean-Francois Masson
چکیده

A simple anion metathesis in diluted aqueous carbonate at room temperature affords 1-(12-mercaptododecyl)-3-methyl-imidazolium carbonate (MDMI-HCO(3)) from MDMI salts self-assembled on gold films and nanoparticles. The properties of MDMI-SAM differ from MDMI in solution, for which the anion exchange reaction does not proceed.

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عنوان ژورنال:
  • Chemical communications

دوره 47 38  شماره 

صفحات  -

تاریخ انتشار 2011